Thermal Expansion In Liquids And Gases

Thermal Expansion In Liquids And Gases

Let's discuss one by one briefly

Thermal Expansion Liquid

The particles of liquid are less tightly packed when compared to solids. Liquids have the ability to take the shape of the container in which liquids are kept. The particles of liquid have less space between them to move so the compression liquids are difficult but not as in solids. The Volume of Liquid is fixed but the shape of Liquid is not fixed. The rate of Diffusion in liquids is higher as compared to solids. Example: water, milk, coffee, blood etc.

Thermal Expansion Gas

The particles of gas are far from each other. The force of attraction between the particles of gases is almost negligible and hence they can move independently. The volume and shape of the gas are not fixed. The particles of gas have more space between them to move so the compression gases are easy. The rate of diffusion is higher as compared to solids and liquids. Examples: air, oxygen, nitrogen, carbon dioxide, etc.

Thermal Expansion in Liquids

Like solids, liquids do not have linear and superficial expansion but liquid only undergoes volume expansion.

We always need some solid vessel to keep the liquid, so liquids are always to be heated along with a vessel which contains them so initially on heating the system (System is liquid + vessel here). Initially, the level of liquid in the vessel falls (vessel expands more since it absorbs heat and liquid expands less) as the volume expansion coefficient of solid is more than that of liquid but later on, it starts rising due to faster expansion of the liquid (because now solid transfer all the heat to liquid and that is the condition of steady-state)

So, from above we can conclude that the actual increase in the volume of the liquid = The apparent increase in the volume of liquid + the increase in the volume of the vessel.

Basically, liquids have two coefficients of volume expansion -

Co-efficient of apparent expansion ${\gamma }_a$: It is due to an apparent (Apparent means that appears but not real) increase in the volume of liquid. This happens when the expansion of the vessel containing the liquid is not taken into account.

${\gamma }_a=\frac{\text{Apparent expansion in volume}}{\text{Initial vdume}\times \mathrm{\Delta }\theta }=\frac{(\mathrm{\Delta }V{)}_o}{V\times \mathrm{\Delta }\theta }$
Co-efficient of real expansion ${\gamma }_r$ : It is due to the actual increase in the volume of liquid due to heating. In this expansion of vessel containing the liquid is taken into account.

${\gamma }_r=\frac{\text{Real increase in volume}}{\text{Initial vdume}\times \mathrm{\Delta }\theta }=\frac{(\mathrm{\Delta }V)}{V\times \mathrm{\Delta }\theta }$
Also coefficient of expansion of flask ${\gamma }_{\text{vessel}}=\frac{\mathrm{\Delta }{V}_{\text{vessel}}}{V\times \mathrm{\Delta }\theta }$
So, ${\gamma }_{\text{Real}}={\gamma }_{\text{Apporent}}+{\gamma }_{\text{Vessel}}$
So the change (apparent change) in volume in liquid relative to the vessel is -

$\mathrm{\Delta }{V}_{app}=V{\gamma }_{\text{app}}\mathrm{\Delta }\theta =V({\gamma }_{\text{Real}}-{\gamma }_{\text{Vessel}})\mathrm{\Delta }\theta =V({\gamma }_r-3\alpha )\mathrm{\Delta }\theta$

Where, $\alpha =$ Coefficient of linear expansion of the vessel.

Anomalous expansion of water: Generally any material expands on heating and contracts on cooling. But in the case of water, it expands on heating if its temperature is greater than 4°C. In the range 0°C to 4°C, water contracts on heating and expands on cooling, i.e. $\gamma$ is negative. So water has this special property, which is not found in any existing natural material. This behaviour of water in the range from 0°C to 4°C is called anomalous expansion. You can see it with the help of a graph.

This is the anomalous behaviour of water which causes ice to form first at the surface of a lake in cold weather. So, as winter approaches, the water temperature increases initially at the surface. It results in the water sinking because of its increased density. Consequently, the surface reaches 0°C first and because of that the lake becomes covered with ice. This property of water makes the aquatic life survive the cold winter as the lake bottom remains unfrozen at a temperature of about 4°C.

At 4°C, the density of water is maximum while its specific volume is minimum.

Variation of Density with Temperature -

Most substances (solid and liquid) expand heat is supplied to them, i.e., the volume of a given mass of a substance increases on heating, so the density should decrease $($ as $\rho \propto \frac{1}{V})$ . It means that the density is inversely proportional to the volume. From that, we can deduce the expression of density after heating or cooling as follows -
$\frac{{\rho }^{\prime }}{\rho }=\frac{V}{V^{\prime \prime }}=\frac{V}{V+\mathrm{\Delta }V}=\frac{V}{V+\gamma V\mathrm{\Delta }\theta }=\frac{1}{1+\gamma \mathrm{\Delta }\theta }$

So,

$\Rightarrow {\rho }^{\prime }=\frac{\rho }{1+\gamma \mathrm{\Delta }\theta }=\rho (1+\gamma \mathrm{\Delta }\theta {)}^{-1}=\rho (1-\gamma \mathrm{\Delta }\theta )$
Here, $\rho$ and ${\rho }^{\prime }$ is the density before and after heating the material

Expansion of Gases

As we know the gases have no definite shape. It takes the shape of the vessel in which it is kept. Therefore gases have only volume expansion. Since the expansion of the container (Because the container is solid) is negligible in comparison to the gases, therefore gases have only real expansion.

Coefficient of volume expansion: At constant pressure, the unit volume of a given mass of a gas, increases with a 1°C rise of temperature, which is called the coefficient of volume expansion.

$\alpha =\frac{\mathrm{\Delta }V}{V_0}\times \frac{1}{\mathrm{\Delta }\theta }\Rightarrow$ Final volume $V^{\prime }=V(1+\alpha \mathrm{\Delta }\theta )$
Coefficient of pressure expansion :

$\beta =\frac{\mathrm{\Delta }P}{P}\times \frac{1}{\mathrm{\Delta }\theta }$

$\therefore$ Final pressure $P^{\prime }=P(1+\beta \mathrm{\Delta }\theta )$

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Solved Examples Based On Thermal Stress And Thermal Strain

Example 1: When a liquid in a glass vessel is heated its apparent expansion is $\underset{―}{10.30\times {10}^{-4}/{}^{\circ }\mathrm{C}}$. The same liquid when heated in a metal vessel its apparent expression is $10.06\times {10}^{-4}/{}^{\circ }\mathrm{C}$. The coefficient of linear expansion of the metal is $(\alpha =9\times {10}^{-6}/{}^{\circ }\mathrm{C})$
1) $51\times {10}^{-6}/{}^{\circ }\mathrm{C}$
2) $43\times {10}^{-6}/{}^{\circ }\mathrm{C}$
3) $25\times {10}^{-6}/{}^{\circ }\mathrm{C}$
4) $17\times {10}^{-6}/{}^{\circ }\mathrm{C}$

Solution: As we learned

Co-efficient of Apparent Expansion -

$\begin{array}{rl}& {\gamma }_a=\frac{\text{Apparent expansion in Volume}}{\text{Initial volume}\times \mathrm{\Delta }\theta }\\ & {\gamma }_a=\frac{(\mathrm{\Delta }v{)}_a}{V\times \mathrm{\Delta }\theta }\\ & r_r=r_a+r_g=r_a(\text{inmetal})+r_m\\ & \text{(in glass)}\\ & r_m=r_a\text{(in glass)}-r_a(\text{inmetal})+r_g\\ & =(10.30-10.06)\times {10}^{-4}+3\times 9\times {10}^{-6}\\ & =51\times {10}^{-6}/{}^{\circ }\mathrm{C}\\ & {\alpha }_m=17\times {10}^{-6}/{}^{\circ }\mathrm{C}\end{array}$

Example 2: A glass flask of volume 1 litre is fully filled with mercury at $0^{\circ }\mathrm{C}$. Both the flask and mercury now heated to $100{}^{\circ }\mathrm{C}$ if the coefficient of volume expansion of mercury is $1.82\times {10}^{-4}/{}^{\circ }\mathrm{C}$ the volume coefficient of the linear expansion of glass is ${10}^{-5}/{}^{\circ }\mathrm{C}$ the amount of mercury (in ml ) spilt out is

1) 15.2

2) 17.2

3) 19.2

4) 21.2

Solution:

Co-efficient of Real Expansion flask -

$$\begin{array}{rl}& {\gamma }_{\text{vessel}}=\frac{(\mathrm{\Delta }V{)}_{\text{vessel}}}{V\times \mathrm{\Delta }T}\\ & \mathrm{\Delta }V=V_0({\gamma }_m-{\gamma }_g)\mathrm{\Delta }T\\ & =1000\mathrm{ml}(1.82\times {10}^{-4}-3\times {10}^{-5})\times 100\\ & =15.2\mathrm{ml}\end{array}$$

Example 3: A liquid with a coefficient of volume expansion $\gamma$ is filled in a container of a material having coefficient of linear expansion $\alpha$. If the liquid overflows on heating, then

1) $\gamma =3\alpha$
2) $\gamma >3\alpha$
3) $\gamma <3\alpha$
4) $\gamma ={\alpha }^3$

Solution:

As we learned

Thermal Expansion in Liquids -

Liquid have only volume expansion.

- wherein

Since the liquid overflows, the volume expansion of the liquid is more than that of the material of the container.

Example 4: The level of liquid kept in a vessel will fall on heating if

1) ${\gamma }_{app}=0$
2) ${\gamma }_{\text{app}}>0$
3) ${\gamma }_{app}<0$

4) none of the above

Solution:

As we know,

Expansion (Real gamma less than gamma vessel) -

${\gamma }_{app}<0$

$\mathrm{\Delta }{V}_{app}$ is negative
wherein

The level of liquid in the vessel will fall on heating.

Example 5: The real coefficient of expansion of liquid is 5 times the volume coefficient of expansion of the vessel. The ratio of real and apparent expansion of the liquid is

1) $\frac{4}{5}$
2) $\frac{7}{6}$
3) $\frac{4}{3}$
4) $\frac{5}{4}$

Solution:

$\begin{array}{l}{\gamma }_{\text{app}}^2{\gamma }_{\text{real}}^{-}{\gamma }_{\text{vessel}}^2=5{\gamma }_{\text{resel}}^{\ast }-{\gamma }_{\text{vesse}}^2=4{\gamma }_{\text{vessel}}\\ r_{\text{real}}=5{\gamma }_{\text{vesse}}& k_{\text{real}}=\frac{5}{4}\\ r^2\text{app}=4r_{\text{ressel}}& {\gamma }_{\text{addapp}}\end{array}$

Summary

Thermal stresses are created in a material due to temperature changes and its restraint from expansion or contraction, resulting in internal forces; thermal strain is deformation caused by such stresses. All materials expand upon heating and contract upon cooling. That is, if this movement is restrained, it creates stress.