Emf Of A Cell

Emf Of A Cell

Vishal kumarUpdated on 02 Jul 2025, 05:52 PM IST

The electromotive force (EMF) of a cell is a fundamental concept in the study of electricity, particularly in understanding how cells and batteries power everyday devices. EMF represents the energy provided by a cell to move charges through a circuit, creating an electric current. Imagine the battery in your smartphone, which powers the device by converting chemical energy into electrical energy, enabling it to function. Just like the heart pumps blood to sustain life, the EMF acts as the driving force that pushes electrons through the circuit, ensuring that electrical appliances like fans, lights, and computers operate smoothly. Understanding the EMF of a cell is crucial not only for academic purposes but also for appreciating the underlying principles that govern the functioning of nearly all modern electronic devices. In this article, we will discuss the concept of Emf of A Cell. Electric current is the flow of electric charge through a conductor. This means that an electric current in a circuit is initiated by our continuous action or vibration of an atom as a result of force or the stimulus of another atom when contact is made with external conditions especially the source of Motive Force – Electromotive Force (EMF).

This Story also Contains

  1. What is a Cell?
  2. Electromotive Force (Emf) of a Cell
  3. Potential Difference
  4. Solved Examples Based on Cell and Emf of a Cell

What is a Cell?

A cell, in the context of electricity, is a device that converts chemical energy into electrical energy. It consists of two electrodes (an anode and a cathode) immersed in an electrolyte, a substance that conducts electricity. When the cell is connected to a circuit, a chemical reaction occurs between the electrodes and the electrolyte, which generates an electric current. This current flows through the circuit, powering electrical devices.

The Direction of Flow of Current

  1. inside the cell is from negative to positive electrode

  2. while outside the cell is from positive to negative electrode.

Electromotive Force (Emf) of a Cell

It is the work done / energy carried by a unit charge passing through one complete cycle of the circuit.

E=W/q

unit of emf is volt.

The EMF of a cell is also known as the potential difference across the terminals of a cell when it does not give any current.

Note- Cell is a source of constant emf but not constant current.

Potential Difference

It is the work done / energy carried by the unit charge passing through the external part (excluding the cell ) of the circuit.

The potential difference is equal to the product of the current and the resistance of that given part.

i.e. $V_{A B}=i R$.

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Solved Examples Based on Cell and Emf of a Cell

Example 1: In the circuit shown, current (in A) through the 50 V and 30 V batteries are, respectively

1) 2.5 and 3

2) 3.5 and 2

3) 4.5 and 1

4) 3 and 2.5

Solution:

KVL in loop abgha
$
\begin{aligned}
20 \mathrm{I}_1 & =50 \\
\mathrm{I}_1 & =2.5 \mathrm{~A}
\end{aligned}
$

KVL in loop abcdefgha
$
\begin{aligned}
& 50-5 I_2-30-5 I_2=0 \\
& I_2=2 \mathrm{~A}
\end{aligned}
$

KVL in loop cdefc
$
\begin{aligned}
& 30=10\left(\mathrm{I}_2+\mathrm{I}_3\right) \\
& \Rightarrow \mathrm{I}_2+\mathrm{I}_3=3 \\
& \mathrm{I}_3=3-2=1 \mathrm{~A}
\end{aligned}
$

therefore Current through 50 V battery is $=\mathrm{I}_1+\mathrm{I}_2=2.5+2.0=4.5 \mathrm{~A}$ current through 30 V battery $=\mathrm{I}_3=1 \mathrm{~A}$

Hence, the answer is the option (3).

Example 2:

In the above circuit value of R=10 r. If a total current of 1A is flowing through the circuit the value of E is?

1) 10 r
2) $11 r$
3) $9 r$
4) 0

Solution:

Electromotive force (Emf) of a cell

It is the work done / energy carried by a unit charge passing through one complete cycle of the circuit.

E=W/q

unit of emf is volt.

$\begin{aligned} & \frac{E}{10 r+r}=1 \\ & E=11 r\end{aligned}$

Hence, the answer is the option (2).

Example 3: A cell E1 of emf 6V and internal resistance $2 \Omega$ is connected with another cell E2 of emf 4V and internal resistance $8 \Omega$ ( as shown in the figure). The potential difference across points X and Y is:

1) 3.6V

2) 5.6V

3) 10.0 V

4) 2.0V

Solution:

The figure given in the question can be redrawn as given below

The direction of current in the circuit will be as shown in the figure.
So point Y is at a higher potential than X.
So $\mathrm{V}_{\mathrm{Y}}>\mathrm{V}_{\mathrm{X}}$
Current(I) in circuit,
$
\mathrm{I}=\frac{\mathrm{E}_1+\mathrm{E}_2}{\mathrm{r}_1+\mathrm{r}_2}=\frac{(6-4) \mathrm{V}}{(2+8) \Omega}=0.2 \mathrm{amp}
$

For positive potential $A$ is near to positive terminal of $E_2$ so has +4 V$
So potential across $\mathrm{E}_1$ and $\mathbf{E}_2$
$
\begin{aligned}
& \mathrm{E}_1=\mathrm{V}-\mathrm{Ir}_1=6-0.2 \times 2=6-0.4=5.6 \mathrm{~V} \\
& \mathrm{E}_2=\mathrm{V}+\mathrm{Ir}_2=4+0.2 \times 8=4+1.6=5.6 \mathrm{~V}
\end{aligned}
$

So potential between X and $\mathrm{Y}=E_2=5.6$ Volt.

Hence, the answer is the option (2).

Example 4:

In the above circuit value of R= 10 ohm and r= 1 ohm. If a total current of 1A is flowing through the circuit the potential drop (in V) across R is?

1) 10

2) 9

3) 11

4) 0

Solution:

Potential difference (V) It is the work done / energy carried by unit charge passing through the external part (excluding the cell ) of the circuit.

The potential difference is equal to the product of the current and the resistance of that given part.

i.e. $V_{A B}=i R$.
$
V=I R=10 \mathrm{~V}
$

Hence, the answer is the option (1).

Example 5: A voltmeter of resistance $1000 \Omega$ is connected across resistance $500 \Omega$ in a given circuit. What will be the reading of the voltmeter?

1) 4

2) 2

3) 6

4) 1

Solution:

$
\begin{aligned}
R_{e q} & =\frac{1000 * 500}{1500}+500 \\
& =500+\frac{1000}{3}=\frac{2500}{3} \Omega \\
I & =\frac{10}{\left(\frac{2500}{3}\right)} A=\frac{3}{250} A
\end{aligned}
$

Potential Difference across Voltmeter
$
\begin{aligned}
& \mathrm{V}=\mathbb{R} \\
& I_v=\left(\frac{3}{250}\right) \cdot \frac{R_2}{R_1+R_2}=\left(\frac{3}{250}\right) * \frac{500}{1500} \\
& I_v=\frac{1}{250} \mathrm{~A} \\
& \text { Potential Difference }=\frac{1}{250} * 1000 \mathrm{~V}=4 \mathrm{~V}
\end{aligned}
$

Summary

The EMF of a cell is the driving force that enables the flow of electric current in a circuit by converting chemical energy into electrical energy. The potential difference, which is the work done by a unit charge, depends on the current and resistance within the circuit. Understanding these concepts is key to solving problems related to electric circuits, such as determining current flow, potential differences, and the behaviour of batteries and resistors in various configurations.

Frequently Asked Questions (FAQs)

Q: Can a cell with higher EMF always deliver more power than one with lower EMF?
A:
Not necessarily. While a higher EMF provides greater potential for power delivery, the actual power output also depends on the cell's internal resistance and the external load. A cell with lower EMF but also lower internal resistance might deliver more power in some situations.
Q: What's the relationship between a cell's EMF and the maximum current it can provide?
A:
While EMF doesn't directly limit the maximum current, it plays a role. The maximum current is determined by the EMF divided by the total resistance (internal + external). A higher EMF allows for potentially higher currents, but internal resistance is often the limiting factor.
Q: How does the EMF of a cell relate to its reversibility?
A:
The EMF of a cell is directly related to its reversibility. In a perfectly reversible cell, the EMF would remain constant during charge and discharge cycles. Real cells show some variation due to irreversible processes and internal changes.
Q: Can the EMF of a cell be increased by external means?
A:
The intrinsic EMF of a cell, determined by its chemical components, cannot be increased externally. However, cells can be connected in series to increase the total EMF of the battery system.
Q: What's the significance of the standard EMF in electrochemistry?
A:
The standard EMF, measured under standard conditions (1M concentrations, 1 atm pressure, 25°C), provides a reference point for comparing different electrochemical cells and predicting the direction of spontaneous reactions.
Q: Can a cell have a higher terminal voltage than its EMF?
A:
No, a cell cannot have a higher terminal voltage than its EMF under normal operating conditions. The terminal voltage is always less than or equal to the EMF due to internal voltage drops when current flows.
Q: How does the concept of EMF apply to thermoelectric devices?
A:
In thermoelectric devices, the EMF is generated by the Seebeck effect, where a temperature difference creates a potential difference. The EMF in this case is proportional to the temperature difference between the hot and cold junctions.
Q: How does the EMF of a cell relate to its ability to do work?
A:
The EMF of a cell represents its maximum ability to do electrical work per unit charge. It's a measure of the cell's potential to drive current through a circuit and power electrical devices.
Q: What's the relationship between a cell's EMF and its short-circuit current?
A:
The short-circuit current of a cell is determined by its EMF divided by its internal resistance. A higher EMF or lower internal resistance will result in a higher short-circuit current.
Q: How does pressure affect the EMF of a cell?
A:
For most cells, pressure has minimal effect on EMF. However, in cells where gases are involved in the reactions (like fuel cells), pressure can affect the EMF according to the Nernst equation, with higher pressures generally increasing the EMF.