After the failure of Rutherford's atomic model many scientists started working to give an appropriate model which could overcome the flaws of Rutherford's model. Among such scientists, Neils Bohr was successful in giving the answers to the questions which were put forward by the Rutherford's model of atom.
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It is observed that all elements give characteristic line spectra which could not be explained on the basis of Rutherford's nuclear model of atom. In order to understand line spectrum, it is essential to understand the nature of light (or radiant energy) which in turn was explained first on the basis of 'Electromagnetic wave theory' and then by 'Planck's quantum theory'. Hence, a new model of atom, called Bohr's model of atom, was put forward. This model of atom was able to explain the drawback of Rutherford's model of atom and the main lines of the hydrogen spectrum.
In this article, we will cover the concept of Electromagnetic Waves and several related parameters. This concept falls under the broader category of Atomic structure, which is a crucial chapter in Class 11 chemistry. It is not only essential for board exams but also for competitive exams like the Joint Entrance Examination (JEE Main), National Eligibility Entrance Test (NEET), and other entrance exams such as SRMJEE, BITSAT, WBJEE, BCECE, and more.
Let us discuss Electromagnetic waves and several parameters related to the wave such as Wavelength, period, frequency, and speed as the related formula.
James Maxwell (1870) gave the explanation about the interaction between the charged bodies and the behaviour of electric and magnetic fields on macroscopic level.
Light and other forms of radiant energy that propagates in the form of waves are called electromagnetic waves or electromagnetic radiations. These waves are produced by a charged body moving in a magnetic field or a magnet moving in an electric field. Maxwell first revealed that light waves are associated with oscillating electric and magnetic character.
The main points of this theory are as follows:
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There are several parameters required to characterize or define a wave. These parameters are defined below:
1. Wavelength ($\lambda$): It is the distance travelled by the wave during one complete oscillation.
The maxima are called crests and the minima are called Troughs. Alternatively, the distance between two consecutive crests or two consecutive troughs is also called the wavelength.
2. Time Period (T): It is the time required for one complete oscillation or one complete cycle by a wave.
3. Frequency ($\nu$) : It is the number of waves produced by the source in one second
It is the inverse of the period. Its S.I unit is Hertz (Hz).
$v=1 / T$
4. Velocity (v): It is the distance travelled by the wave in one second.
$
\text { Velocity }=\text { Frequency } X \text { Wavelength }
$
$
C=v \lambda
$
The speed of all the different components of light is the same i.e. they travel with the speed of $3 \times 10^8 \mathrm{~m} / \mathrm{s}$. Their frequency and wavelength are different.
5. Wave number ($\bar{v}$): It is the inverse of the wavelength. It can also be defined as the number of wavelengths present in unit length.
$\bar{v}$ $
=1 / \lambda
$
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The arrangement of the various types of electromagnetic radiations in the order of their increasing wavelengths or decreasing frequencies is known as electromagnetic spectrum.
The rays present on the left extreme of the spectrum have the greatest frequency, least wavelength, and the greatest energy, As the frequency increases, wavelength decreases, and energy increases.
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Example 1: Which of the following EM radiation lies in the highest energy region?
1) UV rays
2) X-rays
3) γ−rays
4) Radio waves
Solution:
Wavelength of electromagnetic radiation:
Radiowave - greater than 109 Angstrom
Microwave -109 to 106 Angstrom
Infrared - 106 to 7000 Angstrom
Visible light- 7000 to 40000 Angstrom
Ultraviolet - 4000 to 10 Angstrom
X-rays - 10 to 0.1 Angstrom
Gamma rays - less than 0.1 Angstrom
Now, The Relation between Energy and Wavelength of EM Waves,
E=hν=hc/λ
E∝1/λ
The energy of the EM wave is in the following order:
γ rays > X - rays > UV rays> visible rays> Infrared rays> microwave > radio wave
Hence, the answer is the option(3).
Example 2: The value of Planck's constant is 6.63×10−34J-s. The velocity of light is 3.0×108 ms−1. Which value is closest to the wavelength in nanometers of a quantum of light with a frequency of 8×1015s−1
1) 3×107
2) 2×10−25
3) 5×10−18
4) 37.5
Solution:
We know that,
$\begin{aligned} & \mathrm{v}=\mathrm{c} \lambda \Rightarrow \lambda=\mathrm{c} / \mathrm{v} \\ & \Rightarrow \lambda=\mathrm{c} / \mathrm{v}=3 \times 10^8 / 8 \times 10^{15}=3.75 \times 10^{-8} \mathrm{~m}=3.75 \times 10^{-8} \mathrm{x} \\ & 10^9 \mathrm{~nm}=4 \times 10 \mathrm{~nm}\end{aligned}$
Hence, the answer is the option (4).
Example 3: Assertion: Electromagnetic waves can be polarised.
Reasoning: The direction of the electric field vector in an electromagnetic wave determines its polarization.
1) Both assertion and reasoning are true, and the reasoning is the correct explanation of the assertion.
2) Both assertion and reasoning are true, but the reasoning is not the correct explanation of the assertion.
3) The assertion is true, but the reasoning is false.
4)Both assertion and reasoning are false.
Solution:
An electromagnetic wave consists of oscillating electric and magnetic fields that are perpendicular to each other and the direction of propagation of the wave. The direction of the electric field vector in an electromagnetic wave determines its polarization. If the electric field vector oscillates in a single plane, the wave is said to be polarised. Electromagnetic waves can be polarised by using a polarising filter, which transmits only the waves that have their electric field vectors oriented in a particular direction. Therefore, both the assertion and reasoning are true, and the reasoning is the correct explanation of the assertion.
Hence, the answer is the option (1).
Example 4:
Following figure shows spectrum of an ideal black body at four different temperatures. The number of correct statement/s from the following is________________. [JEE Main 2023]
A. $\mathrm{T}_4>\mathrm{T}_3>\mathrm{T}_2>\mathrm{T}_1$
B. The black body consists of particles performing simple harmonic motion.
C. The peak of the spectrum shifts to shorter wavelength as temperature increases.
D. $\frac{T_1}{v_1}=\frac{T_2}{v_2}=\frac{T_3}{v_3} \neq$ constant
E. The given spectrum could be explained using quantisation of energy.
1) 2
2) 3
3) 4
4) 1
Solution:
(A) $\mathrm{T}_4>\mathrm{T}_3>\mathrm{T}_2>\mathrm{T}_1$
(C) The peak of the spectrum shift to shorter wavelength of temp. Inc.
Hence, the answer is the option (1).
Frequently Asked Questions (FAQs)
c= distance time = Wavelength Time Period =λT
Electromagnetic waves or EM waves are the source of energy that travels in free space and does not require a medium to propagate. it has a dual nature one is wave nature and another particle nature which is called photons.
The audible spectrum for the human ear is 20 to 20,000 Hz
X-rays play very crucial roles in different fields such as security scanning, dental imaging, in medical imaging 1. Radiography, 2. CT scan or computed Tomography.
Red light and Blue light.