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Definite Integral - Calculus

Definite Integral - Calculus

Edited By Komal Miglani | Updated on Jul 02, 2025 07:44 PM IST

Definite integral as the limit of a sum is one of the important parts of Calculus, which applies to measuring the change in the function at a certain point. Mathematically, it forms a powerful tool by which slopes of functions are determined, the maximum and minimum of functions found, and problems on motion, growth, and decay, to name a few. These concepts of integration have been broadly applied in branches of mathematics, physics, engineering, economics, and biology.

Definite Integral - Calculus
Definite Integral - Calculus

In this article, we will cover the concept of Definite integral as the limit of a sum . This concept falls under the broader category of Calculus, which is a crucial Chapter in class 12 Mathematics. It is not only essential for board exams but also for competitive exams like the Joint Entrance Examination (JEE Main), and other entrance exams such as SRMJEE, BITSAT, WBJEE, BCECE, and more. Over the last ten years of the JEE Main exam (from 2013 to 2023), thirteen questions have been asked on this concept, including six in 2021, one in 2018, three in 2022, and four in 2023.

Definite integral as the limit of a sum

Definite integration calculates the area under a curve between two specific points on the x-axis.

Let f be a function of x defined on the closed interval [a, b] and F be another function such that $\frac{d}{d x}(F(x))=f(x)$ for all x in the domain of f, then

$\int_a^b f(x) d x=[F(x)+c]_a^b=F(b)-F(a)$is called the definite integral of the function f(x) over the interval [a, b], where a is called the lower limit of the integral and b is called the upper limit of the integral.

Let f(x) be a continuous real-valued function defined on the closed interval [a, b] which is divided into n parts as shown in the figure.

Each subinterval denoted as $\left[x_0, x_1\right],\left[x_1, x_2\right], \ldots\left[x_{i-1}, x_i\right], \ldots,\left[x_{n-1}, x_n\right]$ having equal width $\frac{b-a}{n}$ where, $x_0=a$ and $x_n=b$.

$
\Rightarrow \quad x_i-x_{i-1}=\frac{b-a}{n} \quad \text { for } i=1,2,3, \ldots, n
$

We denote the width of each subinterval with the notation $\Delta x$, so $\quad \Delta x=\frac{b-a}{n}$ and $x_i=x_0+i \Delta x$

On each subinterval,$\left.x_{i-1}, x_i\right]$ (for $\left.i=1,2,3, \ldots, n\right)$ a rectangle is constructed with width Δx and height equal to$f\left(x_{i-1}\right)$ which is the function value at the left endpoint of the subinterval. Then the area of this rectangle is s $f\left(x_{i-1}\right) \Delta x$. Adding the areas of all these rectangles, we get an approximate value for A

$\begin{aligned} A \approx L_n & =f\left(x_0\right) \Delta x+f\left(x_1\right) \Delta x+\cdots+f\left(x_{n-1}\right) \Delta x \\ & =\sum_{i=1}^n f\left(x_{i-1}\right) \Delta x\end{aligned}$

$\mathrm{L}_n$ to denote that this is a left-endpoint approximation of A using n subintervals.

The second method for approximating the area under a curve is the right-endpoint approximation. It is almost the same as the left-endpoint approximation, but now the heights of the rectangles are determined by the function values at the right of each subinterval.

This time the height of the rectangle is determined by the function value f(xi) at the right endpoint of the subinterval. Then, the area of each rectangle is f(xi)Δx and the approximation for A is given by

$\begin{aligned} A \approx R_n & =f\left(x_1\right) \Delta x+f\left(x_2\right) \Delta x+\cdots+f\left(x_n\right) \Delta x \\ & =\sum_{i=1}^n f\left(x_i\right) \Delta x\end{aligned}$


As $\mathrm{n} \rightarrow \infty$ strips become narrower and narrower, it is assumed that the limiting values of $L_n$ and $R_n$ are the same in both cases and the common limiting value is the required area under the curve.

Symbolically, we write

$\begin{aligned} & \lim _{n \rightarrow \infty} \mathrm{L}_n=\lim _{n \rightarrow \infty} \mathrm{R}_{\mathrm{n}}=\text { area of the region }=\int_a^b f(x) d x \\ & \int_a^b f(x) d x=\lim _{n \rightarrow \infty} \sum_{i=1}^n f\left(x_i\right) \Delta x=\lim _{n \rightarrow \infty} \sum_{i=1}^n\left(\frac{b-a}{n}\right) f\left(a+\left(\frac{b-a}{n}\right) i\right) \\ & \text { where, } \quad \Delta x=\frac{b-a}{n} \text { and } x_i=x_0+\Delta x . i\end{aligned}$

NOTE:

  1. If $\mathrm{a}=0, \mathrm{~b}=1$, then

$\int_0^1 f(x) d x=\lim _{n \rightarrow \infty} \sum_{i=0}^{n-1} \frac{1}{n} f\left(\frac{i}{n}\right)$

  1. From the definition of definite integral, we have

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$\lim _{n \rightarrow \infty} \frac{1}{n} \sum_{i=\varphi(n)}^{\psi(n)} f\left(\frac{i}{n}\right)=\int_a^b f(x) d x$, where
(i) $\quad \Sigma$ is replaced by $\int$ sign
(ii) $\frac{i}{n}$ is replaced by $x$
(iii) $\frac{1}{n}$ is replaced by $d x$
(iv) To obtain the limits of integration, we use $\mathrm{a}=\lim _{\mathrm{n} \rightarrow \infty} \frac{\phi(\mathrm{n})}{\mathrm{n}}$ and $\mathrm{b}=\lim _{\mathrm{n} \rightarrow \infty} \frac{\psi(\mathrm{n})}{\mathrm{n}}$

For example:

$\begin{aligned} & \lim _{n \rightarrow \infty} \sum_{r=1}^{p . n} \frac{1}{n} f\left(\frac{r}{n}\right)=\int_\alpha^\beta f(x) d x \\ & \text { where, } \alpha=\lim _{n \rightarrow \infty} \frac{r}{n}=0(\text { as } r=1) \\ & \text { and } \quad \beta=\lim _{n \rightarrow \infty} \frac{r}{n}=p(\text { as } r=p n)\end{aligned}$

Recommended Video Based on Definite Integral as the Limit of a Sum


Solved Example Based on Definite integral as the limit of a sum:

Example 1: $\int_0^3\{x\} d x$

1) 2

2) 3/2

3) 4

4) 5

Solution

As we learned

Definite Integrals as the limit of a sum -

$\int_0^l f(x) d x=\lim _{x \rightarrow \infty} \sum \frac{1}{x} f\left(\frac{r}{x}\right)$

Or

$\int_a^b f(x) d x=\lim _{x \rightarrow \infty} h \sum_{r=0}^x f(a+r h)$

- wherein

Where $f(x)$ is a continuous function in $[0, l]$

Where $h=\frac{b-a}{x}$ And $f(x)$ is continuous in $[a, b]$

$\int_0^3\{x\}=\int_0^1\{x\} d x+\int_1^2\{x\} d x+\int_2^3\{x\} d x$

$=3 / 2$

Example 2: $\lim _{n \rightarrow \infty}\left[\frac{1}{n}+\frac{n}{(n+1)^2}+\frac{n}{(n+2)^2}+\ldots \ldots \ldots \ldots \ldots+\frac{n}{(2 n-1)^2}\right]$ is equal to:

1) $\frac{1}{2}$
2) 1
3) $\frac{1}{3}$
4) $\frac{1}{4}$

Solution

$\lim _{n \rightarrow \infty}\left[\frac{1}{n}+\frac{n}{(n+1)^2}+\frac{n}{(n+2)^2}+\ldots+\frac{n}{(2 n-1)^2}\right]$

$\begin{aligned} & =\lim _{n \rightarrow \infty} \sum_{r=0}^{n-1} \frac{n}{(n+r)^2}=\lim _{n \rightarrow \infty} \sum_{r=0}^{n-1} \frac{n}{n^2+2 n r+r^2} \\ & =\lim _{n \rightarrow \infty} \frac{1}{n} \sum_{r=0}^{n-1} \frac{1}{(r / n)^2+2(r / n)+1}\end{aligned}$

$=\int_0^1 \frac{\mathrm{dx}}{(\mathrm{x}+1)^2}=\left[\frac{-1}{(\mathrm{x}+1)}\right]_0^1=\frac{1}{2}$

Hence, the answer is the option (1).

Example 3: $\left.\lim _{n \rightarrow \infty}\left(\frac{(n+1)^{\frac{1}{3}}}{(n)^{\frac{4}{3}}}\right)+\frac{(n+2)^{\frac{1}{3}}}{(n)^{\frac{4}{3}}}+\ldots \ldots \ldots+\frac{(2 n)^{\frac{1}{3}}}{(n)^{\frac{4}{3}}}\right)$ is equal to:

1) $\frac{3}{4}(2)^{\frac{4}{3}}-\frac{3}{4}$
2) $\frac{4}{3}(2)^{\frac{4}{3}}$
3) $\frac{3}{4}(2)^{\frac{4}{3}}-\frac{4}{3}$
4) $\frac{4}{3}(2)^{\frac{3}{4}}$

Solution

$\lim _{n \rightarrow \infty}\left(\frac{(n+1)^{\frac{1}{3}}}{(n)^{\frac{4}{3}}}+\frac{(n+2)^{\frac{1}{3}}}{(n)^{\frac{4}{3}}}+\ldots \ldots \ldots \ldots+\frac{(2 n)^{\frac{1}{3}}}{(n)^{\frac{4}{3}}}\right)$

$=\lim _{n \rightarrow \infty} \frac{1}{n}\left[\left(1+\frac{1}{n}\right)^{\frac{1}{3}}+\left(1+\frac{2}{n}\right)^{\frac{1}{3}}+\ldots \ldots \ldots+\left(1+\frac{n}{n}\right)^{\frac{1}{3}}\right]$

$\begin{aligned} & =\frac{1}{n} \sum_{r=1}^n\left(1+\frac{r}{n}\right)^{\frac{1}{3}} \\ & =\int_0^1(1+x)^{\frac{1}{3}} d x=\frac{3}{4}\left(2^{\frac{4}{3}}-1\right)\end{aligned}$

Hence, the answer is option (1).

Example 4: $\lim _{n \rightarrow \infty}\left(\frac{n^2}{\left(n^2+1\right)(n+1)}+\frac{n^2}{\left(n^2+4\right)(n+2)}+\frac{n^2}{\left(n^2+9\right)(n+3)}+\ldots+\frac{n^2}{\left(n^2+n^2\right)(n+n)}\right)$

1) $\frac{\pi}{8}+\frac{1}{4} \log _e 2$
2) $\frac{\pi}{4}+\frac{1}{8} \log _e 2$
3) $\frac{\pi}{4}-\frac{1}{8} \log _{\mathrm{e}} 2$
4) $\frac{\pi}{8}+\log _c \sqrt{2}$

Solution:

$\lim _{n \rightarrow \infty}\left(\frac{n^2}{\left(n^2+1\right)(n+1)}+\frac{n^2}{\left(n^2+4\right)(n+2)}+\cdots+\frac{n^2}{\left(n^2+n^2\right)(n+n)}\right)$

$=\lim _{n \rightarrow \infty} \sum_{r=1}^n \frac{n^2}{\left(n^2+r^2\right)(n+r)}$

$=\int_0^1 \frac{1}{\left(1+x^2\right)(1+x)} d x$

$\begin{aligned} & =\frac{1}{2} \int_0^1 \frac{1}{1+x} d x+\frac{1}{2} \int_b^1 \frac{d x}{1+x^2}-\frac{1}{4} \int_0^1 \frac{2 x}{\left(1+x^2\right)} d x \\ & =\frac{1}{2}[\ln (1+x)]_0^1+\frac{1}{2}\left[\tan ^{-1} x\right]_0^1-\frac{1}{4}\left[\ln \left(1+x^2\right)\right]_0^1 \\ & =\frac{1}{2} \ln 2+\frac{\pi}{8}-\frac{1}{4} \ln 2 \\ & =\frac{\pi}{8}+\frac{1}{4} \log e^2\end{aligned}$

Hence, the answer is the option (1).

Example 5: If $\lim _{n \rightarrow \infty} \frac{(n+1)^{k-1}}{n^{k+1}}[(n k+1)+(n k+2)+\ldots+(n k+n)$$=33 \cdot \lim _{n \rightarrow \infty} \frac{1}{n^{k+1}} \cdot\left[1^k+2^k+3^k+\ldots+n^k\right]$,

then the integral value of $k$ is equal to _______.

1) 5

2) 9

3) 8

4) 6

Solution

$\lim _{n \rightarrow \infty} \frac{(n+1)^{k-1}}{n k+1}[n k \cdot n+1+2+\cdots+n]$

$=\lim _{\mathrm{n} \rightarrow \infty} \frac{(\mathrm{n}+1)^{\mathrm{k}-1}}{\mathrm{n}^{\mathrm{k}+1}} \cdot\left[\mathrm{n}^2 \mathrm{k}+\frac{(\mathrm{n}(\mathrm{n}+1)}{2}\right]$

$\lim _{n \rightarrow \infty} \frac{(n+1)^{k-1} \cdot n^2\left(k+\frac{\left(1+\frac{1}{n}\right)}{2}\right)}{n k+1}$

$\lim _{n \rightarrow \infty}\left(1+\frac{1}{n}\right)\left(k+\frac{\left(1+\frac{1}{n}\right)}{2}\right)$

$\Rightarrow\left(k+\frac{1}{2}\right)$

RHS

$\Rightarrow \lim _{\mathrm{n} \rightarrow \infty} \frac{1}{\mathrm{nk}+1}\left(1^{\mathrm{k}}+2^{\mathrm{k}}+\cdots+\mathrm{h}^{\mathrm{k}}\right)=\frac{1}{\mathrm{k}+1}$

LHS=RHS

$\Rightarrow \mathrm{k}+\frac{1}{2}=33 \cdot \frac{1}{\mathrm{k}+1}$

$\begin{aligned} & \Rightarrow(2 k+1)(k+1)=66 \\ & \Rightarrow(k-5)(2 k+13)=0 \\ & \Rightarrow k=5 \text { or } \frac{13}{9}\end{aligned}$

Hence, the answer is the (5).

Frequently Asked Questions (FAQs)

1. What is a definite integral and how does it differ from an indefinite integral?
A definite integral is a specific numerical value that represents the area between a function and the x-axis over a defined interval. It differs from an indefinite integral, which is a family of antiderivatives without specific boundaries. The definite integral has fixed upper and lower limits, while the indefinite integral includes a constant of integration.
2. Can a definite integral ever be negative? If so, what does it represent geometrically?
Yes, a definite integral can be negative. Geometrically, a negative definite integral represents the negative of the area between the function and the x-axis. This occurs when the function is below the x-axis for the majority of the integration interval, or when the area below the x-axis is larger than the area above it within the given bounds.
3. How does changing the order of integration limits affect the result of a definite integral?
Changing the order of integration limits reverses the sign of the definite integral. If ∫[a to b] f(x)dx = K, then ∫[b to a] f(x)dx = -K. This property is known as the reversal of limits theorem. It's because integrating from a higher value to a lower value is equivalent to moving backwards, thus negating the result.
4. What is the geometric interpretation of a definite integral?
Geometrically, a definite integral represents the signed area between the graph of a function and the x-axis over a specified interval. "Signed area" means that areas above the x-axis are considered positive, while areas below are negative. This interpretation helps visualize the meaning of integration and its connection to area calculation.
5. How can you evaluate a definite integral if you don't know the antiderivative of the function?
When the antiderivative is unknown or difficult to find, there are several methods to evaluate a definite integral:
6. How does the Fundamental Theorem of Calculus connect derivatives and definite integrals?
The Fundamental Theorem of Calculus establishes a crucial link between derivatives and definite integrals. It states that if F(x) is an antiderivative of f(x), then the definite integral of f(x) from a to b is equal to F(b) - F(a). This theorem allows us to evaluate definite integrals using antiderivatives, bridging the gap between differentiation and integration.
7. What is the significance of the Mean Value Theorem for Integrals?
The Mean Value Theorem for Integrals states that for a continuous function f(x) on the interval [a,b], there exists at least one point c in (a,b) such that f(c) = (1/(b-a)) * ∫[a to b] f(x)dx. This theorem guarantees that the average value of the function over the interval equals the function's value at some point within that interval, connecting the integral to a specific point on the function.
8. Can you explain the difference between proper and improper integrals?
Proper integrals are definite integrals where both the function and the limits of integration are finite. Improper integrals, on the other hand, involve either:
9. What is the significance of the Second Fundamental Theorem of Calculus?
The Second Fundamental Theorem of Calculus states that the derivative of an integral function F(x) = ∫[a to x] f(t)dt is the original function f(x). This theorem establishes that integration and differentiation are inverse operations, allowing us to differentiate definite integrals with respect to their limits. It's crucial for solving differential equations and understanding the relationship between rates of change and accumulation.
10. What is the significance of improper integrals with infinite limits in physics and engineering?
Improper integrals with infinite limits are crucial in physics and engineering for:
11. What is the relationship between definite integrals and Taylor series?
Definite integrals and Taylor series are related in several ways:
12. How do definite integrals relate to the concept of flux in vector calculus?
In vector calculus, flux is often represented as a surface integral, which is an extension of the definite integral to higher dimensions. The flux Φ of a vector field F through a surface S is given by: Φ = ∫∫S F · dS. This integral accumulates the component of the vector field passing through each infinitesimal area of the surface, demonstrating how definite integrals extend to more complex geometric and physical concepts.
13. What is the significance of the Leibniz integral rule in evaluating definite integrals?
The Leibniz integral rule, also known as differentiation under the integral sign, allows us to differentiate a definite integral with respect to a parameter affecting its limits or integrand. It states: d/dx [∫[a(x) to b(x)] f(t,x) dt] = f(b(x),x) * b'(x) - f(a(x),x) * a'(x) + ∫[a(x) to b(x)] ∂f/∂x dt. This rule is crucial for:
14. How does the concept of a Riemann sum relate to definite integrals?
A Riemann sum is a method of approximating the area under a curve by dividing it into rectangles. As the number of rectangles approaches infinity and their width approaches zero, the Riemann sum converges to the definite integral. This concept forms the foundation for understanding definite integrals as the limit of a sum, bridging discrete approximations with continuous areas.
15. How does the concept of accumulation function relate to definite integrals?
An accumulation function F(x) = ∫[a to x] f(t)dt represents the accumulated area under the curve of f(t) from a fixed lower limit a to a variable upper limit x. This function directly relates to the definite integral, as it shows how the integral value changes as the upper limit varies. The derivative of the accumulation function equals the original function, illustrating the Fundamental Theorem of Calculus.
16. What is the physical significance of a definite integral in real-world applications?
Definite integrals have numerous physical interpretations, including:
17. How do you interpret the units of a definite integral?
The units of a definite integral are the product of the units of the function being integrated and the units of the variable of integration. For example, if you're integrating velocity (m/s) with respect to time (s), the result will have units of meters (m). This interpretation helps in understanding the physical meaning of the integral in applied problems.
18. What is the relationship between definite integrals and area between curves?
The area between two curves y = f(x) and y = g(x) from x = a to x = b can be calculated using definite integrals as: ∫[a to b] |f(x) - g(x)| dx. This formula represents the absolute difference between the two functions, integrated over the specified interval. It demonstrates how definite integrals can be used to compute complex areas by breaking them down into simpler regions.
19. How does the concept of average value of a function relate to definite integrals?
The average value of a function f(x) over an interval [a,b] is given by: (1/(b-a)) * ∫[a to b] f(x)dx. This formula uses the definite integral to calculate the mean value of the function over the interval. It's equivalent to finding the height of a rectangle with the same width and area as the region under the curve, illustrating how integrals can be used to compute averages.
20. How do definite integrals relate to the concept of net change?
Definite integrals can represent the net change of a quantity over an interval. If f(x) represents the rate of change of a quantity Q with respect to x, then the definite integral ∫[a to b] f(x)dx gives the net change in Q from x = a to x = b. This interpretation is useful in various applications, such as calculating net displacement from velocity or net population change from growth rates.
21. What is the importance of the additivity property of definite integrals?
The additivity property states that ∫[a to c] f(x)dx = ∫[a to b] f(x)dx + ∫[b to c] f(x)dx for any point b between a and c. This property allows us to split integrals into smaller parts or combine them, which is crucial for:
22. How does the concept of definite integrals extend to multivariable calculus?
In multivariable calculus, definite integrals extend to multiple dimensions:
23. What is the role of definite integrals in probability theory?
In probability theory, definite integrals are used to:
24. How can definite integrals be used to solve differential equations?
Definite integrals are used in solving differential equations through:
25. How does the concept of definite integrals relate to the idea of work in physics?
In physics, work is defined as the integral of force over displacement: W = ∫[a to b] F(x) dx. This definite integral represents:
26. How do definite integrals relate to the concept of path independence in conservative vector fields?
In conservative vector fields, the work done (represented by a line integral) is path-independent. This property is closely related to definite integrals:
27. What is the role of definite integrals in defining and understanding special functions?
Many special functions in mathematics are defined or can be represented using definite integrals:
28. How do definite integrals contribute to the study of Fourier series and transforms?
Definite integrals are fundamental in Fourier analysis:
29. What is the significance of definite integrals in defining and working with moments in statistics and mechanics?
Moments in statistics and mechanics are often defined using definite integrals:
30. How do definite integrals relate to the concept of work-energy theorem in physics?
The work-energy theorem, which states that the work done on an object equals its change in kinetic energy, is fundamentally related to definite integrals:
31. What is the role of definite integrals in defining and understanding probability density functions?
Definite integrals are crucial in probability theory for working with continuous probability distributions:

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Arrange the following Cobalt complexes in the order of incresing Crystal Field Stabilization Energy (CFSE) value. Complexes :  

\mathrm{\underset{\textbf{A}}{\left [ CoF_{6} \right ]^{3-}},\underset{\textbf{B}}{\left [ Co\left ( H_{2}O \right )_{6} \right ]^{2+}},\underset{\textbf{C}}{\left [ Co\left ( NH_{3} \right )_{6} \right ]^{3+}}\: and\: \ \underset{\textbf{D}}{\left [ Co\left ( en \right )_{3} \right ]^{3+}}}

Choose the correct option :
Option: 1 \mathrm{B< C< D< A}
Option: 2 \mathrm{B< A< C< D}
Option: 3 \mathrm{A< B< C< D}
Option: 4 \mathrm{C< D< B< A}

The type of hybridisation and magnetic property of the complex \left[\mathrm{MnCl}_{6}\right]^{3-}, respectively, are :
Option: 1 \mathrm{sp ^{3} d ^{2} \text { and diamagnetic }}
Option: 2 \mathrm{sp ^{3} d ^{2} \text { and diamagnetic }}
Option: 3 \mathrm{sp ^{3} d ^{2} \text { and diamagnetic }}
Option: 4 \mathrm{sp ^{3} d ^{2} \text { and diamagnetic }}
Option: 5 \mathrm{d ^{2} sp ^{3} \text { and diamagnetic }}
Option: 6 \mathrm{d ^{2} sp ^{3} \text { and diamagnetic }}
Option: 7 \mathrm{d ^{2} sp ^{3} \text { and diamagnetic }}
Option: 8 \mathrm{d ^{2} sp ^{3} \text { and diamagnetic }}
Option: 9 \mathrm{d ^{2} sp ^{3} \text { and paramagnetic }}
Option: 10 \mathrm{d ^{2} sp ^{3} \text { and paramagnetic }}
Option: 11 \mathrm{d ^{2} sp ^{3} \text { and paramagnetic }}
Option: 12 \mathrm{d ^{2} sp ^{3} \text { and paramagnetic }}
Option: 13 \mathrm{sp ^{3} d ^{2} \text { and paramagnetic }}
Option: 14 \mathrm{sp ^{3} d ^{2} \text { and paramagnetic }}
Option: 15 \mathrm{sp ^{3} d ^{2} \text { and paramagnetic }}
Option: 16 \mathrm{sp ^{3} d ^{2} \text { and paramagnetic }}
The number of geometrical isomers found in the metal complexes \mathrm{\left[ PtCl _{2}\left( NH _{3}\right)_{2}\right],\left[ Ni ( CO )_{4}\right], \left[ Ru \left( H _{2} O \right)_{3} Cl _{3}\right] \text { and }\left[ CoCl _{2}\left( NH _{3}\right)_{4}\right]^{+}} respectively, are :
Option: 1 1,1,1,1
Option: 2 1,1,1,1
Option: 3 1,1,1,1
Option: 4 1,1,1,1
Option: 5 2,1,2,2
Option: 6 2,1,2,2
Option: 7 2,1,2,2
Option: 8 2,1,2,2
Option: 9 2,0,2,2
Option: 10 2,0,2,2
Option: 11 2,0,2,2
Option: 12 2,0,2,2
Option: 13 2,1,2,1
Option: 14 2,1,2,1
Option: 15 2,1,2,1
Option: 16 2,1,2,1
Spin only magnetic moment of an octahedral complex of \mathrm{Fe}^{2+} in the presence of a strong field ligand in BM is :
Option: 1 4.89
Option: 2 4.89
Option: 3 4.89
Option: 4 4.89
Option: 5 2.82
Option: 6 2.82
Option: 7 2.82
Option: 8 2.82
Option: 9 0
Option: 10 0
Option: 11 0
Option: 12 0
Option: 13 3.46
Option: 14 3.46
Option: 15 3.46
Option: 16 3.46

3 moles of metal complex with formula \mathrm{Co}(\mathrm{en})_{2} \mathrm{Cl}_{3} gives 3 moles of silver chloride on treatment with excess of silver nitrate. The secondary valency of CO in the complex is_______.
(Round off to the nearest integer)
 

The overall stability constant of the complex ion \mathrm{\left [ Cu\left ( NH_{3} \right )_{4} \right ]^{2+}} is 2.1\times 10^{1 3}. The overall dissociation constant is y\times 10^{-14}. Then y is ___________(Nearest integer)
 

Identify the correct order of solubility in aqueous medium:

Option: 1

Na2S > ZnS > CuS


Option: 2

CuS > ZnS > Na2S


Option: 3

ZnS > Na2S > CuS


Option: 4

Na2S > CuS > ZnS


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