Law of Equivalence: Definition, Formula, Questions and Examples

Law of Equivalence: Definition, Formula, Questions and Examples

Edited By Shivani Poonia | Updated on Jul 02, 2025 07:41 PM IST

Thus, inventors resort to patent systems for the protection of their works against unauthorized usage by contemporaries using the fast-evolving landscape of innovation and technological development. But in so doing, the very nature of the evolution of the technology has made it very difficult—indeed well-nigh impossible—to ascertain with full precision the exact scope of the patent claim. Such is the place of the Doctrine of Equivalents—a legal device to protect a patentee, even in the face of additional ways to infringe, either by device or process, that are not within the literally expressed scope of the patent claim.

This Story also Contains
  1. Doctrine of Equivalents
  2. Types of Equivalents
  3. Application in real life and its implication
  4. Some Solved Examples
  5. Conclusion
Law of Equivalence: Definition, Formula, Questions and Examples
Law of Equivalence: Definition, Formula, Questions and Examples

The Doctrine of Equivalents is designed to prevent courts from finding a party not infringing when the accused product or process is only insubstantially different from the patented invention, not allowing an infringer to steal the benefits of the invention by concocting minor changes to avoid literal infringement. The discussion that follows will, therefore, make the points of the Doctrine of Equivalents very crystal clear regarding basic principles, many dimensions, and some practical real-world applications in both the business and academic worlds.

Doctrine of Equivalents

The core idea behind the Equivalents Doctrine is that a patent cannot be restricted to the literal terms or parameters but extends further to include equivalents of the claimed invention. It has been interpreted to mean that even a device or process otherwise performing a function the same way and achieving nearly the same result as the patented invention shall be an equivalent even though given a different name or is differently shaped or formed. The doctrine is designed to withhold a person who violates the claims of the patent from making "a copy of the benefit of the invention" by small and immaterial variations.

Laws of Equivalence

According to the law of equivalence, for each and every reactant and product,
Equivalents of each reactant reacted = Equivalents of each product formed.

Example,
Suppose the reaction is taking place as follows:
$P+Q \rightarrow R+S$

According to the law of equivalence,

Equivalents of P reacted = Equivalents of Q reacted = Equivalents of R produced = Equivalents of S produced

Equivalents of any substance = (Weight of substance (in g)) / (Equivalent weight)
= Normality (N) x Volume (V) (In liter)
Normality (N) = n-Factor x Molarity (M)

Law of Equivalence finds great importance in Acid-base Neutralisation Reactions as well as Redox Titrations.

Here we shall be mainly covering the Acid-Base neutralization reactions in detail.

Types of Equivalents

The Doctrine of Equivalents really reflects two principal types of equivalents: (1) Insubstantial Differences and (2) Known Interchangeability.
Insubstantial differences are those changes that are so minor or inconsequential that they would not make a material difference in how the invention works. Known interchangeability refers to those cases where persons skilled in the art would have known that one element could have been replaced by another without affecting how the invention works.

Application in real life and its implication


The Doctrine of Equivalents has a vital application in the practical world.
It provides protection to the patentee against those infringing entities that otherwise would not infringe per se the patent in question but would remain substantially similar to the invention. For instance, if a certain company invents a new drug, the competitor cannot make some minor modifications to the formula associated with that drug and sell it under a different patent, under the Doctrine of Equivalents. The Doctrine of Equivalents is a point of rigorous study and discussion within the parameters of academia.
By using those case studies, the students will appreciate the delicate balance to be struck between providing adequate protection to the patentees and clearly notifying the public of the scope of the patent. It will also discuss the developed tests and legal bars in a bid to limit the application of the doctrine, such as the Festo Presumption and the All Elements Rule.

Recommended topic video on(Law of Equivalence)

Some Solved Examples

Example 1:In this equation:

$2 \mathrm{KClO}_3 \rightarrow 2 \mathrm{KCl}+3 \mathrm{O}_2$
What will be the mass (in g) of O2 produced from 1.23g of KClO3?

1) (correct)0.482

2)0.545

3)0.758

4)0.345

Solution

According to the equation,

2 moles of KClO3 will produce 3 moles of O2.

Thus moles of KClO3 = 1.23 / 123= 0.01 moles

Therefore, 0.01 moles of KClO3 will produce = (3 x 0.01) / 2= 0.015 moles

thus mass of O2 = 0.015 x 32
= 0.48g

Hence, the answer is the option (1).

Example 2:
50 mL of 0.5 M oxalic acid is needed to neutralize 25 mL of sodium hydroxide solution. What is the mass (in g) of NaOH in 50 mL of the given sodium hydroxide solution?

1) 20

2)4(Correct)

3)10

4)40

Solution

$\begin{aligned} & \mathrm{H}_2 \mathrm{C}_2 \mathrm{O}_4+2 \mathrm{NaOH} \rightarrow \mathrm{Na}_2 \mathrm{C}_2 \mathrm{O}_4+2 \mathrm{H}_2 \mathrm{O} \\ & \text { meq of } \mathrm{H}_2 \mathrm{C}_2 \mathrm{O}_4=\text { meq } \mathrm{NaOH} \\ & 50 \times 0.5 \times 2=25 \mathrm{M} \mathrm{NaOH} \times 1 \\ & 1000 \mathrm{ml} \text { solution }=2 \times 240 \mathrm{gram} \mathrm{NaOH} \\ & \therefore 50 \mathrm{ml} \text { sol }=4 \mathrm{~g} \mathrm{NaOH}\end{aligned}$

Hence, the answer is the option (2).

Example 3:
The volume of 0.1 N dibasic acid sufficient to neutralize 1 g of a base that furnishes 0.04 mol of OH− in aqueous solution is:

1) 200mL

2)400mL(Correct)

3)600mL

4)800mL

Solution

Dibasic acids mean acids have two ionizable hydrogens.

gram eq. of OH- = mole $\times$ n-factor = 0.04 $\times$ 1 = 0.04

The Law of equivalence we get,
milli equivalents of acid = milli equivalents of base

N1 X V1 (ACID) = ( meq. of base)

0.1×V = ( meq. of base)

0.1 X V = ( meq. of base) = 0.04 $\times$ 1000

V x 0.1 = 40
V = 400ml

Hence, the answer is an option (2).

Example 4:
How much NaOH is required to neutralize 1500 mL of 0.1 M HCl?

1) 40g

2)4g

3)6g(correct)

4)60g

Solution

According to the law of Equivalence,

meq. of HCl = meq. of NaOH

$\therefore$ 1500 $\times$ 0.1 = moles of NaOH (as n-factor of NaOH =1)

$\therefore$ moles of NaOH = 150

$\therefore$ Weight of NaOH = 6 g

Hence, the answer is the option (3).

Example 5:
To neutralize 20 mL of M10 sodium hydroxide, the volume of M20 hydrochloric acid required is:

1) 10ml

2)15ml

3)20ml

4)40ml(correct)

Solution

According to the law of equivalence,

meq. of HCl = meq. of NaOH

$\begin{aligned} & \therefore 20 \times \frac{1}{10}=\mathrm{V} \times \frac{1}{20} \\ & \mathrm{~V}=40 \mathrm{ml}\end{aligned}$

Hence, the answer is the option (4).

Conclusion

The Doctrine of Equivalents becomes an astonishing aspect of patent law in serving to protect against infringement, which will assure that the system of patents continues to encourage and reward innovation. Exponential technological progress, with all its consequent changes, shall have an impact upon us all, so will the Doctrine of Equivalents be an essential tool in the arsenal of patent holders who are looking to protect their invention from infringement but at the same time ensure there is a fair and competitive marketplace.

Frequently Asked Questions (FAQs)

1. How does the equivalent weight of an element change in different compounds?
The equivalent weight of an element can change in different compounds because it depends on the valency or oxidation state of the element in that specific compound. For example, the equivalent weight of iron in FeCl2 is different from its equivalent weight in FeCl3.
2. Why is the Law of Equivalence important in stoichiometry?
The Law of Equivalence is crucial in stoichiometry because it allows us to predict the quantities of reactants and products in chemical reactions. It helps in calculating the exact proportions of elements that will react, ensuring accurate predictions of reaction outcomes.
3. Can you explain the concept of equivalent weight using an example?
Certainly! Consider the reaction between zinc and hydrochloric acid: Zn + 2HCl → ZnCl2 + H2. The equivalent weight of zinc in this reaction is its atomic weight (65.38 g/mol) divided by 2, as it replaces two hydrogen atoms. So, the equivalent weight of zinc is 32.69 g/mol.
4. How does the Law of Equivalence relate to Dalton's Atomic Theory?
The Law of Equivalence supports Dalton's Atomic Theory by reinforcing the idea that elements combine in fixed ratios. This aligns with Dalton's concept that atoms of different elements combine in simple whole-number ratios to form compounds.
5. What's the relationship between normality and molarity?
Normality (N) is related to molarity (M) through the equation: N = M × Number of equivalents per mole. This relationship shows that normality takes into account the number of reactive species in a solution, while molarity only considers the number of moles of solute per liter of solution.
6. What is the Law of Equivalence in chemistry?
The Law of Equivalence states that elements combine with each other in the ratio of their equivalent weights or in simple multiples of their equivalent weights. This law helps us understand how elements react and form compounds in fixed proportions.
7. How does the concept of equivalent weight apply to precipitation reactions?
In precipitation reactions, equivalent weights help determine the exact quantities of reactants needed to completely precipitate a substance. The Law of Equivalence ensures that the number of equivalents of cations equals the number of equivalents of anions in the precipitate.
8. Can you explain why the equivalent weight of H2SO4 is half its molecular weight?
The equivalent weight of H2SO4 is half its molecular weight because it has two replaceable hydrogen ions. In reactions, it can donate two protons or react with two moles of a monovalent base. Therefore, its equivalent weight is its molecular weight (98 g/mol) divided by 2, which is 49 g/mol.
9. Why is it important to specify the reaction when discussing equivalent weights?
Specifying the reaction is crucial when discussing equivalent weights because the same element or compound can have different equivalent weights depending on the reaction context. For example, the equivalent weight of H2SO4 in a neutralization reaction is different from its equivalent weight in a reaction where it acts as an oxidizing agent.
10. How does the Law of Equivalence help in understanding the concept of limiting reagents?
The Law of Equivalence helps in identifying limiting reagents by allowing us to compare the number of equivalents of each reactant present. The reactant with the fewest number of equivalents will be completely consumed first and is therefore the limiting reagent.
11. What is the formula for calculating equivalent weight?
The general formula for equivalent weight is: Equivalent Weight = Molar Mass / Valency. For acids, it's Molar Mass / Number of replaceable H+ ions. For bases, it's Molar Mass / Number of replaceable OH- ions. For oxidizing or reducing agents, it's Molar Mass / Change in oxidation number.
12. What is meant by the term "gram equivalent"?
A gram equivalent is the mass in grams of a substance that is chemically equivalent to 1 mole of hydrogen ions in a reaction. It's calculated by dividing the molar mass of the substance by its valency or the number of electrons transferred in a redox reaction.
13. How is equivalent weight different from atomic weight?
Equivalent weight is the mass of an element that combines with or displaces 1.008 grams of hydrogen or 8 grams of oxygen. Atomic weight is the average mass of an atom of an element relative to 1/12 the mass of a carbon-12 atom. Equivalent weight is context-dependent, while atomic weight is a fixed property of an element.
14. Why do we use normality in acid-base titrations?
Normality is used in acid-base titrations because it directly relates to the number of reactive species (H+ or OH-) in a solution. This makes it easier to determine the equivalence point and calculate the amount of acid or base neutralized, regardless of whether the acid or base is monoprotic or polyprotic.
15. How does the Law of Equivalence help in understanding redox reactions?
In redox reactions, the Law of Equivalence helps us understand that the number of electrons transferred is proportional to the equivalent weights of the oxidizing and reducing agents. This allows us to balance redox equations and predict the amounts of reactants needed or products formed.
16. How does the Law of Equivalence relate to Faraday's laws of electrolysis?
The Law of Equivalence is closely related to Faraday's laws of electrolysis. It states that the mass of substance deposited or liberated at an electrode during electrolysis is directly proportional to the quantity of electricity passed and the equivalent weight of the substance.
17. Can you explain how the Law of Equivalence relates to the concept of equivalent conductance in electrochemistry?
The Law of Equivalence is related to equivalent conductance in electrochemistry because both concepts deal with the number of charges carried by ions. Equivalent conductance is the conductance of a solution containing one gram equivalent of electrolyte. The law helps in understanding how the number of charge-carrying species affects the solution's conductivity.
18. Can you explain how the Law of Equivalence relates to the concept of capacity factor in ion exchange chromatography?
The Law of Equivalence is related to the capacity factor in ion exchange chromatography because both deal with the exchange of ions. The capacity factor represents the number of milliequivalents of ions that can be exchanged per gram of resin. The law helps in predicting the amount of sample that can be effectively separated based on the resin's capacity.
19. How does the concept of equivalent weight apply to colligative properties of solutions?
While colligative properties primarily depend on the number of particles in solution, the Law of Equivalence can be relevant when dealing with electrolytes. It helps in calculating the effective number of particles produced when an electrolyte dissociates, which affects properties like freezing point depression and boiling point elevation.
20. How does the concept of equivalent weight apply to the formation of coordination compounds?
In coordination compounds, the equivalent weight of the central metal ion is determined by its oxidation state and the number of coordination sites. The Law of Equivalence helps in predicting the ratio in which the metal ion combines with ligands, ensuring charge balance and determining the overall formula of the complex.
21. Can you explain how the Law of Equivalence relates to the concept of ion activity in solution chemistry?
The Law of Equivalence is related to ion activity in solution chemistry because it helps explain why ions of different charges can have different activities at the same concentration. The law considers the charge of ions, which affects their interactions in solution and thus their effective concentration or activity.
22. Can you explain how the Law of Equivalence relates to the concept of ion pairing in solution?
The Law of Equivalence is relevant to ion pairing in solution because it considers the charges of ions. Ions with higher charges (and thus different equivalent weights) are more likely to form ion pairs due to stronger electrostatic interactions. This affects solution properties and can influence reaction rates and equilibria.
23. How does the Law of Equivalence help in understanding the concept of charge density in ions?
The Law of Equivalence relates to charge density in ions because it considers both the charge and the mass of ions. Ions with higher charge-to-mass ratios (i.e., higher charge densities) often have different chemical behaviors. The law helps explain why ions with similar charges but different sizes can have
24. What's the difference between equivalent weight and equivalent mass?
Equivalent weight and equivalent mass are often used interchangeably, but there's a subtle difference. Equivalent weight is a dimensionless number expressing the ratio of the element's atomic weight to its valency. Equivalent mass is the actual mass in grams of one equivalent of a substance.
25. How does the Law of Equivalence apply to polyprotic acids?
For polyprotic acids, the Law of Equivalence considers each ionizable hydrogen separately. The equivalent weight of a polyprotic acid depends on how many protons it donates in a specific reaction. For example, H3PO4 can have three different equivalent weights depending on whether it donates one, two, or three protons.
26. Can you explain the concept of milliequivalents?
A milliequivalent (mEq) is one-thousandth of an equivalent. It's often used in biological and medical contexts to express the concentration of electrolytes in solutions. Milliequivalents take into account both the mass and the ionic charge of the species, making it useful for comparing ions with different charges.
27. How does the Law of Equivalence help in understanding the concept of normality?
The Law of Equivalence is fundamental to the concept of normality. Normality expresses concentration in terms of gram equivalents per liter of solution, directly relating to the number of reactive species. This makes normality particularly useful in reactions where the number of reactive species is important, such as acid-base or redox reactions.
28. Why is the equivalent weight of NaOH equal to its molecular weight?
The equivalent weight of NaOH is equal to its molecular weight because it has only one replaceable hydroxide ion (OH-). In reactions, one mole of NaOH reacts with one mole of H+ ions or provides one mole of OH- ions. Therefore, its equivalent weight is the same as its molecular weight, which is 40 g/mol.
29. How does the Law of Equivalence apply to gravimetric analysis?
In gravimetric analysis, the Law of Equivalence helps in calculating the amount of analyte present based on the mass of the precipitate formed. By knowing the equivalent weights of the analyte and the precipitate, we can determine the exact relationship between their masses, enabling accurate quantitative analysis.
30. What's the significance of the term "chemically equivalent" in the context of the Law of Equivalence?
"Chemically equivalent" refers to substances that have the same capacity to react or combine with other substances. The Law of Equivalence states that chemically equivalent quantities of different substances will react completely with each other, ensuring that reactions occur in precise, predictable ratios.
31. How does the equivalent weight of a compound change if it acts as an oxidizing agent versus a reducing agent?
The equivalent weight of a compound can change depending on whether it acts as an oxidizing or reducing agent because it's based on the number of electrons transferred. For example, in the reaction 2Fe3+ + Sn2+ → 2Fe2+ + Sn4+, the equivalent weight of iron is different when it's reduced (Fe3+ to Fe2+) compared to when it's oxidized (Fe2+ to Fe3+).
32. How does the Law of Equivalence help in understanding buffer solutions?
The Law of Equivalence is crucial in understanding buffer solutions because it helps determine the relative amounts of acid and conjugate base needed to create an effective buffer. By considering the equivalent weights of the acid and base components, we can calculate the optimal ratios for maximum buffering capacity.
33. Why is it important to consider the Law of Equivalence when balancing redox equations?
The Law of Equivalence is essential in balancing redox equations because it ensures that the number of electrons lost by the reducing agent equals the number of electrons gained by the oxidizing agent. This principle helps in determining the correct stoichiometric coefficients for a balanced redox equation.
34. How does the concept of equivalent weight apply to complex ion formation?
In complex ion formation, the equivalent weight of the central metal ion is determined by its oxidation state in the complex. The Law of Equivalence helps in understanding the ratio in which the metal ion combines with ligands, ensuring charge balance and predicting the stoichiometry of the complex.
35. How does the Law of Equivalence help in understanding the concept of charge balance in aqueous solutions?
The Law of Equivalence is fundamental to the concept of charge balance in aqueous solutions. It ensures that the total positive charge from cations equals the total negative charge from anions. This principle is crucial for maintaining electroneutrality in solutions and helps in predicting the behavior of electrolytes in various chemical processes.
36. Why is the equivalent weight of a salt different in a precipitation reaction compared to an acid-base reaction?
The equivalent weight of a salt can differ between precipitation and acid-base reactions because it depends on the specific ions involved in each reaction. In a precipitation reaction, the equivalent weight is based on the ion that participates in forming the precipitate. In an acid-base reaction, it's based on the ion that accepts or donates a proton.
37. How does the Law of Equivalence apply to the concept of ion exchange capacity in water treatment?
The Law of Equivalence is crucial in understanding ion exchange capacity in water treatment. It helps determine the amount of ions that can be exchanged based on the equivalent weights of the ions involved. This allows for accurate prediction of the resin's capacity to remove specific ions from water and its regeneration requirements.
38. Can you explain how the Law of Equivalence relates to the concept of equivalent fraction in solution chemistry?
The equivalent fraction is the ratio of the number of equivalents of a particular ion to the total number of equivalents of all ions in a solution. The Law of Equivalence ensures that the sum of all equivalent fractions in a solution equals one, maintaining charge balance and helping predict solution properties.
39. How does the Law of Equivalence help in understanding the concept of equivalent ionic radii?
The Law of Equivalence relates to equivalent ionic radii by considering how ions of different charges interact. Ions with the same charge and similar size often have similar chemical properties. The law helps explain why ions with different charges but similar equivalent ionic radii can sometimes substitute for each other in crystal structures.
40. Why is it important to consider the Law of Equivalence when designing galvanic cells?
The Law of Equivalence is crucial in designing galvanic cells because it helps determine the relationship between the amount of reactants consumed and the electrical charge produced. This allows for accurate prediction of cell potential, capacity, and the amount of electrical work that can be done by the cell.
41. Can you explain how the Law of Equivalence relates to the concept of ion selectivity in ion-selective electrodes?
The Law of Equivalence helps in understanding ion selectivity in ion-selective electrodes by considering the charge and size of ions. The selectivity of an electrode is often related to the equivalent weights of the ions involved. Ions with similar equivalent weights may interfere with each other, affecting the electrode's selectivity.
42. How does the Law of Equivalence help in understanding the concept of equivalent conductivity in electrochemistry?
The Law of Equivalence is fundamental to understanding equivalent conductivity in electrochemistry. Equivalent conductivity is the conductance of a solution containing one gram equivalent of electrolyte. The law helps explain why ions with different charges can have different contributions to the overall conductivity of a solution.
43. Why is it important to consider the Law of Equivalence when dealing with polyelectrolytes?
The Law of Equivalence is crucial when dealing with polyelectrolytes because these molecules can have multiple charged groups. The law helps in determining the effective charge and equivalent weight of the polyelectrolyte, which can vary depending on factors like pH and ionic strength of the solution.
44. How does the Law of Equivalence help in understanding the concept of equivalent fraction in mixed electrolyte solutions?
In mixed electrolyte solutions, the Law of Equivalence helps in calculating the equivalent fraction of each ion species. This is crucial for predicting solution properties and understanding how different ions contribute to the overall behavior of the solution, such as its conductivity or colligative properties.
45. Why is it important to consider the Law of Equivalence when dealing with amphoteric substances?
The Law of Equivalence is important when dealing with amphoteric substances because these can act as both acids and bases. The equivalent weight of an amphoteric substance can change depending on whether it's acting as an acid or a base in a particular reaction, affecting stoichiometric calculations and reaction predictions.
46. How does the concept of equivalent weight apply to the formation of double salts?
In the formation of double salts, the Law of Equivalence helps in understanding how different ions combine in specific ratios. The equivalent weights of the constituent ions determine the stoichiometry of the double salt, ensuring charge balance and helping predict the formula of the resulting compound.

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