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Dear Aspirant,
Yes, biology as an additional subject is eligible for giving NEET Exam.
you must have passed in English and in both the theory and practical of PCB i.e Physics, Chemistry and Biology with at least 50 % in aggregate of PCB in 12th examination if belong to general category , or at least 40% in aggregate of PCB if belongs to Obc/ Sc /st.
For more details-
NEET Eligibility Criteria 2021 - Qualification, Age Limit, Marks Required (careers360.com)
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