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Hello there,
Yes you can start the preparation of NDA from class 12th. As the syllabus for Maths and GS are 11th and 12th standard syllabus. And you can also apply for it while you are in appearing year. There are 2 exams for NDA every year which is conducted by NTA. For better information regarding NDA you can visit our site for which the link is given below:
https://competition.careers360.com/exams/nda
Thank you I hope this information is useful to you.
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