3 Views

How are the following conversions carried out (a)phenol to picric acid (b) phenol to anisole (c)propene to propan 1 ol


Daksh Chauhan 15th Aug, 2025
Answer (1)
Shobhit Chaudhary 22nd Aug, 2025

Hi Student,

Thank you for reaching out!

Methods to carry out the specified chemical conversions mentioned below:

(a) Phenol to Picric Acid : Phenol (C6H5OH) is converted to picric acid (2,4,6-trinitrophenol) through nitration.
Treat phenol with a mixture of concentrated nitric acid (HNO3) and concentrated sulfuric acid (H2SO4) at 60–80C. Sulfuric acid protonates nitric acid to form nitronium ions (NO2 +), which attack the aromatic ring. Initially, phenol forms o-nitrophenol and p-nitrophenol. Further nitration under controlled heating introduces two more nitro groups, yielding 2,4,6-trinitrophenol (picric acid). Cool the mixture, filter, and recrystallize to isolate the yellow crystalline product.

(b) Phenol to Anisole : Phenol is converted to anisole (C6H5OCH3) via Williamson’s ether synthesis.
React phenol with a strong base like sodium hydroxide (NaOH) to form sodium phenoxide (C6H5ONa). Then, treat sodium phenoxide with methyl iodide (CH3I) or dimethyl sulfate in an aprotic solvent like acetone at room temperature. The methoxide group attaches to the phenyl ring, forming anisole. Distill the product to purify it.

(c) Propene to Propan-1-ol : Propene (CH3CH=CH2) is converted to propan-1-ol (CH3CH2CH2OH) via hydroboration-oxidation.
First, react propene with borane (BH3) in tetrahydrofuran (THF) to form trialkylborane. Then, oxidize it with hydrogen peroxide (H2O2) and sodium hydroxide (NaOH) at 0–10 degree Celsius. This anti-Markovnikov addition introduces a hydroxyl group to the less substituted carbon, yielding propan-1-ol. Purify by distillation.

All the best.

Thank you.

Regards,
Careers360 Team

Related Questions

Amity University-Noida B.Tech...
Apply
Among top 100 Universities Globally in the Times Higher Education (THE) Interdisciplinary Science Rankings 2026
Indus University M.Tech Admis...
Apply
Highest CTC 26 LPA | Top Recruiters: Accenture, TCS, Tech Mahindra, Capgemini, Microsoft
MAHE, Manipal - B.Tech Admiss...
Apply
Last Date to Apply: 15th March | NAAC A++ Accredited | Accorded institution of Eminence by Govt. of India | NIRF Rank #3
Greater Noida Institute of Te...
Apply
NAAC A+ Accredited | Highest CTC 70 LPA | Average CTC 6.5 LPA | 400+ Recruiters
Victoria University, Delhi NCR
Apply
Apply for UG & PG programmes from Victoria University, Delhi NCR Campus
Amity University-Noida BBA Ad...
Apply
Among top 100 Universities Globally in the Times Higher Education (THE) Interdisciplinary Science Rankings 2026
View All Application Forms

Download the Careers360 App on your Android phone

Regular exam updates, QnA, Predictors, College Applications & E-books now on your Mobile

150M+ Students
30,000+ Colleges
500+ Exams
1500+ E-books