Hello Student

The Xilinx ISE primarily used for circuit synthesis and design. Where as learning process of Xilinx is pick hardware descriptive language choose a perfect book to learn it. Download the free webpack  Vivado HLX. Read Xilinx document UG 910 to use Vivado HLX. Read Xilinx programming ug900 for teasing vivado simulator to use your HDL program. This is an outline of process of learning XIli NX.

Hope this helps.