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What are the different types of crystalline solids based on the nature of the intermolecular forces/bonding? Give examples of each type.


Sumit Saini 17th Mar, 2021
Answer (1)
Sumit Saini 17th Mar, 2021

Crystalline solids are classified based on the type of bonding between their constituent particles:

  • Molecular Solids: Held together by weak intermolecular forces (Van der Waals, dipole-dipole, or hydrogen bonds). They are generally soft and have low melting points.
    • Non-polar Molecular Solids: (e.g., Argon, Iodine) Held by London Dispersion Forces.
    • Polar Molecular Solids: (e.g., Solid SO2, Solid NH3) Held by Dipole-Dipole interactions.
    • Hydrogen-Bonded Molecular Solids: (e.g., Ice) Held by Hydrogen bonds.
  • Ionic Solids: Held together by strong electrostatic forces between oppositely charged ions. They are hard, brittle, and have high melting points. Example: NaCl, MgO.
  • Metallic Solids: Held together by metallic bonds (a sea of delocalized electrons surrounding positive metal ions). They are good conductors of heat and electricity, malleable, and ductile. Example: Copper, Iron, Silver.
  • Covalent or Network Solids: Atoms are linked by a network of covalent bonds throughout the crystal. They are very hard and have extremely high melting points. Example: Diamond, Graphite, Quartz (SiO2).


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