Yes, NCERT is best book to prepare for JEE Main. It is the most recommended book for your preparation as syllabus is based on them and it helps you to clear your basics. So, that you can easily solve tricky questions.

After, NCERT you can refer below books for your preparation

Physics
H.C. Verma & Resnick Halliday

Chemistry
Morrison & Boyd and O.P. Tandon

Mathematics
R.D. Sharma, Arihant, Hall Knight & S. L. Looney

You should also refer previous year papers and mock test series for your practice to score good marks in JEE Main.

All the Best!!

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