Hello
Yes, you are eligibile for doing class XII again through NIOS in PCB stream.
However, you can not appear for NEET 2020 through it, because your class XII would be completed in 2021 through NIOS.
So, yes, you can appear in NEET examination from 2021 onwards.

However, It is not recommended to reappear for class XII through NIOS beacause it won't provide you with any huge advantage, and in the meantime you complete  your class XII(1 year) you can not take admission to any colleges.
It is better to cboose a course which suits your interests through PCM stream itself.

Good luck

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