Hi Shashank,
In respect of PSUs, ECE is always the better option than the CSE. ECE has a lot of portfolios and opportunities in PSUs like BEL, ISRO, etc.
Even in Placement, ECE has a broader scope, as due to the hybrid nature, ECE Students are eligible to sit for a lot of CSE, EEE, and IT Companies. But, in terms of placement package, CTC, CSE is one notch lead over the ECE.
In terms of higher studies, CSE and ECE both have ample opportunities.
Hope, this information answers your query.
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