See, this is a clear case of what you prefer, a better branch or better college. ECE in VIT, Vellore is a very well known programme and is highly regarded in the industry, while Computer Science Engineering programmes are known to be high paying in nature. If you want an opinion then VIT Vellore will be more preferred than PES Bangalore as companies which come for CSE also allow ECE students to apply, so the opportunities will be greater in VIT than PES.

You can also use our college predictor to see your chances in all the colleges:
https://engineering.careers360.com/jee-main-college-predictor?icn=QnA&ici=qna_answer

Hope I have answered your question. All the best!