For VITEEE you can always provide the preference list for the exam cities, but you can't select the exam center. The organizer will provide you a designated exam center in your 1st preferred city (if not available then they will provide you exam center in your subsequent preferred cities) which will be mentioned in the ADMIT CARD of the examination.

For more information you can consider the link below:

https://engineering.careers360.com/exams/viteee

I hope this helps. Wish you a great eve!