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Yes, the CAP or CAF reservation does apply to VIT AP counselling.

You must go through the state convenor process, not through direct admission, VITEEE, or the management quota.

Make sure you have the following:

A valid defence service certificate

Andhra Pradesh domicile

Properly completed the choice filling during counselling

It also requires more than five years of residence in Andhra Pradesh along with a valid defence certificate.