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Hi Aditya,
Yes, NCERT Exemplar of Class 11th and 12th Maths are useful for JEE Mains. But, NCERT Exemplar is enough to get good marks in board exams, for JEE Mains studying Exemplar is not at all sufficient. You are required to study several other reference books also. Studying NCERT Exemplar for JEE Mains can fetch you around 30% Marks in JEE Main Maths Examination.
Feel free to ask doubts in the Comment Section.
I hope this information helps you.
Good Luck!
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